Sekreterava group

Electron transfer processes within (bio)electrocatalysts and on the electrode/catalyst interface at the molecular level.
Our research
We aim to enhance the understanding of electron transfer processes within (bio)electrocatalysts and on the electrode/catalyst interface at the molecular level, and to design new (bio)electrocatalytic devices based on this new understanding. Our research bridge the disciplines of electrochemistry and (bio)inorganic chemistry and utilizes a range of electrochemical, spectroscopic and theoretical techniques, including single entity electrochemistry, protein film electrochemistry, electron paramagnetic resonance spectroscopy and quantum mechanical calculations, to address fundamental question of relevance to electrocatalysis.
Our current work focuses on investigations of plasmon-driven electrocatalysis at single plasmonic nanoparticles and on development of new single-molecule electrochemical techniques for studies of enzymatic catalysis, particularly focusing on oxygen reduction reaction catalyzed by multicopper oxidases. Other collaborative work include mechanistic studies of hydrogenase catalysis by protein film electrochemistry and examination of heme-based biomimetic catalysts by electron paramagnetic resonance spectroscopy.
Research projects
Group members
Publications
Part of Journal of the American Chemical Society, p. 4654-4666, 2025
- DOI for Probing the Influence of the Protein Scaffold on H-Cluster Reactivity via Gain-of-Function Studies─Improved H2 Evolution and O2 Tolerance through Rational Design of [FeFe] Hydrogenase
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Part of Faraday discussions, p. 384-398, 2025
- DOI for Advanced algorithm for step detection in single-entity electrochemistry: a comparative study of wavelet transforms and convolutional neural networks
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Hot or Not?: Reassessing Mechanisms of Photocurrent Generation in Plasmon‐Enhanced Electrocatalysis
Part of Angewandte Chemie International Edition, 2024
- DOI for Hot or Not?: Reassessing Mechanisms of Photocurrent Generation in Plasmon‐Enhanced Electrocatalysis
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The Potential of Molecular Electrocatalysis for Ammonia-to-Dinitrogen Conversion
Part of ChemElectroChem, 2024
- DOI for The Potential of Molecular Electrocatalysis for Ammonia-to-Dinitrogen Conversion
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From protein film to single-entity protein electrochemistry
Part of Current Opinion in Electrochemistry, 2024
- DOI for From protein film to single-entity protein electrochemistry
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Part of ADVANCED INTELLIGENT SYSTEMS, 2024
- DOI for Automated Analysis of Nano-Impact Single-Entity Electrochemistry Signals Using Unsupervised Machine Learning and Template Matching
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Nano-Impact Single-Entity Electrochemistry Enables Plasmon-Enhanced Electrocatalysis
Part of Angewandte Chemie International Edition, 2023
- DOI for Nano-Impact Single-Entity Electrochemistry Enables Plasmon-Enhanced Electrocatalysis
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Role of an Inert Electrode Support in Plasmonic Electrocatalysis
Part of ACS Catalysis, p. 4110-4118, 2022
- DOI for Role of an Inert Electrode Support in Plasmonic Electrocatalysis
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Oxidative dehalogenation of trichlorophenol catalyzed by a promiscuous artificial heme-enzyme
Part of RSC Advances, p. 12947-12956, 2022
- DOI for Oxidative dehalogenation of trichlorophenol catalyzed by a promiscuous artificial heme-enzyme
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Single-entity electrochemistry of collision in sensing applications
Part of Sensors and Actuators Reports, 2021
- DOI for Single-entity electrochemistry of collision in sensing applications
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Electron Transfer to the Trinuclear Copper Cluster in Electrocatalysis by the Multicopper Oxidases
Part of Journal of the American Chemical Society, p. 17236-17249, 2021
Part of Chemical Science, p. 12789-12801, 2020
- DOI for Characterization of a putative sensory [FeFe]-hydrogenase provides new insight into the role of the active site architecture
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Part of ChemElectroChem, p. 4411-4417, 2019
Bioelectrocatalysis on Anodized Epitaxial Graphene and Conventional Graphitic Interfaces
Part of ChemElectroChem, p. 3791-3796, 2019
Contact
- If you have questions about our research, you are welcome to contact programme professor Gustav Berggren.
- Gustav Berggren