Streuff Group

Overview of the research in Streuff's group. In the middle are the symbols of the catalysts titanium and zirconium. Around these are two arrows that symbolise the catalytic cycle as well as structural formulas for different reactants and products that the research group is working on.

Catalysis, synthesis, organometallics and mechanisms

Our research interests span a wide variety of topics within the area of transition metal catalysis, with current focus on titanium and zirconium catalyzed reactions. We are currently working on new methods for reductive bond couplings and cleavage reactions, the design of new catalysts, and the application of our methods in organic synthesis. In parallel, we are taking a deep look into the reaction mechanisms of the new transformations with the goal to understand their reactivity and selectivity.

Group members

Research leader: Jan Streuff

Group members: Sanne Albers, Marie Deliaval, Orsola Assunta Luongo, Ritu Singh, Viktoryia Smaliak

Publications

Methoxide-Enabled Zirconium-Catalyzed Migratory Alkene Hydrosilylation

Luongo, Orsola A.; Lemmerer, Miran; Albers, Sanne L.; Streuff, Jan

Part of Angewandte Chemie International Edition, 2024
- DOI for Methoxide-Enabled Zirconium-Catalyzed Migratory Alkene Hydrosilylation
- Download full text (pdf) of Methoxide-Enabled Zirconium-Catalyzed Migratory Alkene Hydrosilylation
Photoinduced ring‐opening and phototoxicity of an indolin‐3‐one derivative

Doloczki, Susanne; Kern, Christoph; Holmberg Olausson, Karl; Swartling, Fredrik J. et al.

Part of Chemistry - A European Journal, 2023
- DOI for Photoinduced ring‐opening and phototoxicity of an indolin‐3‐one derivative
- Download full text (pdf) of Photoinduced ring‐opening and phototoxicity of an indolin‐3‐one derivative
An Indolin-3-imine Photobase and pH Sensitive Fluorophore

Doloczki, Susanne; Kern, Christoph; Holmberg, Karl O.; Zhao, Miao et al.

Part of ChemPhotoChem, 2023
- DOI for An Indolin-3-imine Photobase and pH Sensitive Fluorophore
- Download full text (pdf) of An Indolin-3-imine Photobase and pH Sensitive Fluorophore
Reductive Umpolung and Defunctionalization Reactions through Higher-Order Titanium(III) Catalysis

Streuff, Jan

Part of Synlett, p. 314-326, 2023
- DOI for Reductive Umpolung and Defunctionalization Reactions through Higher-Order Titanium(III) Catalysis
A Guide to Low-Valent Titanocene Complexes as Tunable Single-Electron Transfer Catalysts for Applications in Organic Chemistry

Hilche, Tobias; Younas, Sara L.; Gansauer, Andreas; Streuff, Jan

Part of ChemCatChem, 2022
- DOI for A Guide to Low-Valent Titanocene Complexes as Tunable Single-Electron Transfer Catalysts for Applications in Organic Chemistry
- Download full text (pdf) of A Guide to Low-Valent Titanocene Complexes as Tunable Single-Electron Transfer Catalysts for Applications in Organic Chemistry
Catalytic Asymmetric β‐Oxygen Elimination

Matt, Christof; Orthaber, Andreas; Streuff, Jan

Part of Angewandte Chemie International Edition, 2022
- DOI for Catalytic Asymmetric β‐Oxygen Elimination
- Download full text (pdf) of Catalytic Asymmetric β‐Oxygen Elimination
Kinetic Analysis Uncovers Hidden Autocatalysis and Inhibition Pathways in Titanium(III)-Catalyzed Ketone-Nitrile Couplings

Younas, Sara L.; Streuff, Jan

Part of ACS Catalysis, p. 11451-11458, 2021
- DOI for Kinetic Analysis Uncovers Hidden Autocatalysis and Inhibition Pathways in Titanium(III)-Catalyzed Ketone-Nitrile Couplings
- Download full text (pdf) of Kinetic Analysis Uncovers Hidden Autocatalysis and Inhibition Pathways in Titanium(III)-Catalyzed Ketone-Nitrile Couplings