Laurent Duda
Senior Lecturer/Associate Professor at Department of Physics and Astronomy; X-ray Photon Science
- Telephone:
- +46 18 471 35 12
- Mobile phone:
- +46 70 883 63 43
- E-mail:
- laurent.duda@physics.uu.se
- Visiting address:
- Ångströmlaboratoriet, Lägerhyddsvägen 1
- Postal address:
- Box 516
751 20 UPPSALA
Senior Lecturer/Associate Professor at Department of Physics and Astronomy; X-ray Photon Science; Condensed Matter Physics of Energy Materials
- Telephone:
- +46 18 471 35 12
- Mobile phone:
- +46 70 883 63 43
- E-mail:
- laurent.duda@physics.uu.se
- Visiting address:
- Ångströmlaboratoriet, Lägerhyddsvägen 1
- Postal address:
- Box 516
751 20 UPPSALA
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Short presentation
The group of Laurent Duda uses resonant inelastic x-ray scattering to study fundamental processes of Li and Na ion batteries.
Keywords
- resonant inelastic x-ray scattering
Research
My research has focused on the development of synchrotron radiation based techniques for studying the electronic structure of a variety of materials, including a multitude of 3d-transition metal systems such as cuprate superconductors. My methodology of choice is resonant inelastic x-ray scattering (RIXS) combined with x-ray absorption spectroscopy. I have developed tools and platforms for in situ sample handling and operando x-ray spectroscopy experiments at SR beamlines. Examples include the study of atmospheric corrosion and heterogeneous catalysis.
Currently, I collaborate with battery material experts from Sweden (Materials Chemistry) and UK (Oxford and St. Andrews U.) to research fundamental processes in Li and Na ion battery materials using RIXS. In Nature Chemistry, 8(7): 684-691 (2016) we showed that RIXS is sensitive to anionic redox processes. In Nature 577 (7791), 502-508 (2020) high resolution RIXS was pivotal to reveal that layered Li rich ion battery cathodes produce oxygen molecules that are trapped in the crystal upon charging and reversibly re-integrate oxygen into the crystal upon discharge. Generally, the role of oxygen in a variety of cathode material systems is of high interest and RIXS can give unique insights that can benefit the development of future battery generations.
Publications
Recent publications
- Vibrationally-resolved RIXS reveals OH-group formation in oxygen redox active Li-ion battery cathodes (2024)
- The Role of Oxygen in Automotive Grade Lithium-Ion Battery Cathodes (2024)
- The role of anionic processes in Li1−xNi0.44Mn1.56O4 studied by resonant inelastic X-ray scattering (2023)
- Anionic Redox and Electrochemical Kinetics of the Na2Mn3O7 Cathode Material for Sodium-Ion Batteries (2022)
- Importance of Superstructure in Stabilizing Oxygen Redox in P3-Na0.67Li0.2Mn0.8O2 (2022)
All publications
Articles
- Vibrationally-resolved RIXS reveals OH-group formation in oxygen redox active Li-ion battery cathodes (2024)
- The Role of Oxygen in Automotive Grade Lithium-Ion Battery Cathodes (2024)
- The role of anionic processes in Li1−xNi0.44Mn1.56O4 studied by resonant inelastic X-ray scattering (2023)
- Anionic Redox and Electrochemical Kinetics of the Na2Mn3O7 Cathode Material for Sodium-Ion Batteries (2022)
- Importance of Superstructure in Stabilizing Oxygen Redox in P3-Na0.67Li0.2Mn0.8O2 (2022)
- Enhanced Cycling Stability in the Anion Redox Material P3-Type Zn-Substituted Sodium Manganese Oxide (2022)
- Enhanced oxygen redox reversibility and capacity retention of titanium-substituted Na-4/7[1/7Ti1/7Mn5/7]O-2 in sodium-ion batteries (2022)
- Effect of Ti-Substitution on the Properties of P3 Structure Na2/3Mn0.8Li0.2O2 Showing a Ribbon Superlattice (2022)
- Effect of Cu substitution on anion redox behaviour in P3-type sodium manganese oxides (2022)
- How Mn/Ni Ordering Controls Electrochemical Performance in High-Voltage Spinel LiNi0.44Mn1.56O4 with Fixed Oxygen Content (2020)
- Charging Mechanism of Li2MnO3 (2020)
- Understanding the redox process upon electrochemical cycling of the P2-Na0.78Co1/2Mn1/3Ni1/6O2 electrode material for sodium-ion batteries (2020)
- Superstructure control of first-cycle voltage hysteresis in oxygen-redox cathodes (2020)
- Oxygen Redox Activity through a Reductive Coupling Mechanism in the P3-Type Nickel-Doped Sodium Manganese Oxide (2020)
- What Triggers Oxygen Loss in Oxygen Redox Cathode Materials? (2019)
- Understanding charge compensation mechanisms in Na0.56Mg0.04Ni0.19Mn0.70O2 (2019)
- Excess lithium in transition metal layers of epitaxially grown thin film cathodes of Li2MnO3 leads to rapid loss of covalency during first battery cycle (2019)
- Lithium manganese oxyfluoride as a new cathode material exhibiting oxygen redox (2018)
- Polarization-dependent resonant inelastic X-ray scattering study at the Cu L and O K-edges of YBa2Cu3O7-x (2018)
- Oxygen redox chemistry without excess alkali-metal ions in Na2/3[Mg0.28Mn0.72]O2 (2018)
- Transition metal doping effects in Co-phosphate catalysts for water splitting studied with XAS (2018)
- Oxygen redox reactions in Li ion battery electrodes studied by resonant inelastic X-ray scattering (2017)
- Band gap states in nanocrystalline WO3 thin films studied by softx-ray spectroscopy and opticalspectrophotometry (2016)
- Anion Redox Chemistry in the Cobalt Free 3d Transition Metal Oxide Intercalation Electrode Li[Li0.2Ni0.2Mn0.6]O-2 (2016)
- Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen (2016)
- Sulfidation of Single-Phase Oxide on Copper and as Powder Studied Using Soft X-Ray Spectroscopy (2015)
- X-ray absorption spectroscopy and resonant inelastic scattering study of the first lithiation cycle of the Li-ion battery cathode Li-2-xMnSiO4 (2014)
- Combined Experimental and ab initio Multi Reference Configuration Interaction study of the Resonant Inelastic X-RayScattering spectrum of CO2 (2014)
- Self-doping processes between planes and chains in the metal-to-superconductor transition of YBa2Cu3O6.9 (2014)
- Reaction cell for in situ soft x-ray absorption spectroscopy and resonant inelastic x-ray scattering measurements of heterogeneous catalysis up to 1 atm and 250 °C (2013)
- Two-Spinon and Orbital Excitations of the Spin-Peierls System TiOCl (2011)
- Resonant inelastic X-ray scattering and X-ray absorption spectroscopy on the negative electrode material Li0.5Ni0.25TiOPO4 in a Li-ion battery (2011)
- Exposure of Oxidized Copper Surfaces to Aqueous Na2S Solution Studied with Soft X-Ray Spectroscopy (2011)
- Resonant inelastic X-ray scattering and X-ray absorption spectroscopy on the cathode materials LiMnPO4 and LiMn0.9Fe0.1PO4 (2011)
- X-ray absorption spectroscopy on electrochemically oxidized Cu exposed to Na2S (2011)
- Resonant inelastic X-ray scattering and X-ray absorption spectroscopy on the negative electrode material Li0.5Ni0.25TiOPO4 in a Li-ion battery (2011)
- Exposure of Oxidized Copper Surfaces to Aqueous Na2S Solution Studied with Soft X-Ray Spectroscopy (2011)
- Observation of strong resonant behavior in the inverse photoelectron spectroscopy of Ce oxide (2011)
- Observation of strong resonant behavior in the inverse photoelectron spectroscopy of Ce oxide (2011)
- LaAlO3/SrTiO3 oxide heterostructures studied by resonant inelastic x-ray scattering (2010)
- LaAlO3/SrTiO3 oxide heterostructures studied by resonant inelastic x-ray scattering (2010)
- The Initial Stages of Atmospheric Corrosion of Iron in a Saline Environment Studied with Time-Resolved In Situ X-Ray Transmission Microscopy (2010)
- The initial stages of atmospheric corrosion of iron in a saline environment studied with time-resolved in situ x-ray transmission microscopy (2010)
- Resonant Soft X-Ray Emission Spectroscopy and X-Ray Absorption Spectroscopy on the Cathode Material LiNi0.65Co0.25Mn0.1O2 (2010)
- Resonant Soft X-Ray Emission Spectroscopy and X-Ray Absorption Spectroscopy on the Cathode Material LiNi0.65Co0.25Mn0.1O2 (2010)
- System for in situ studies of atmospheric corrosion of metal films using soft x-ray spectroscopy and quartz crystal microbalance (2007)
- Observation of multiple Zhang-Rice excitations in a correlated solid (2007)
- Reply to comment by Hüfner on "Resonant Inelastic X-Ray Scattering at the Oxygen K Resonance of NiO: Nonlocal Charge Transfer and Double-Singlet Excitations" (2006)
- Resonant inelastic x-ray scattering at the oxygen K resonance of NiO: Nonlocal charge transfer and double-singlet excitations (2006)
- Resonant inelastic x-ray scattering at the NiO O K-resonance (2006)
- Large magnetic circular dichroism in rensonant inelastic x-ray scattering at the Mn L-edge of Mn-Zn ferrite (2006)
- Electronic structure of Li-inserted V6O13 battery cathodes: Rigid band behavior and effects of hybridization (2005)
- X-ray yield and selectively excited X-ray emission spectra of atenolol and nadolol. (2005)
- Resonant L-alpha,L-beta X-ray emission and L-3,L-2 X-ray absorption spectra of 3d metals in Co(2)MnZ (Z = Al, Ga, Sn, Sb) Heusler alloys as an element- selective probe of spin character of valence band (2005)
- Resonant soft X-ray emission of solids and liquids (2004)
- Low-energy excitations in resonant inelastic x-ray scattering of alpha(')-NaV2O5 (2004)
- Low-energy excitations in resonant inelastic X-ray scattering of α' - NaV2O5 (2004)
- Li insertion into V6O13 battery cathodes studies by soft x-ray spectroscopies (2004)
- Resonant soft X-ray emission spectroscopy of doped and undoped vanadium oxides (2004)
- Electronic structure studies of V6O13 by soft x-ray emission spectroscopy: Band-like and excitonic vanadium states (2004)
- Resonant soft X-ray emission spectroscopy of doped and undoped vanadium oxides (2004)
- The electronic structure and lithiation of electrodes based on vanadium-oxide nanotubes (2003)
- Redox behavior of vanadium oxide nanotubes as studied by X-ray photoelectron spectroscopy and soft X-ray absorption spectroscopy. (2003)
- Resonant inelastic soft X-ray scattering of insulating cuprates (2002)
- Resonant soft X-ray emission spectroscopy of V2O3, VO2 and NaV2O5 (2002)
- The thermodynamic study of the silica elimination from the high purity water through some ion-exchange deeply overlaid systems (2002)
- Sub-band gap electronic states in nanocrystalline WO3 thin films studied by soft x-ray spectroscopy, optical absorption spectroscopy and density functional calculations
- Band gap states in nanocrystalline WO3 thin films studied by soft x-ray spectroscopy, optical absorption spectroscopy and density functional calculations
- X-ray spectroscopic studies of selected Cu(II) compounds exposed to dilute sulfide solutions
- In situ soft x-ray spectroscopy of ethylene epoxidation over Ag at 1 atm and 230°C
Chapters
- Soft x-ray emission and resonant inelastic x-ray scattering spectroscopy (2006)
- Soft x-ray fluorescence spectroscopy for materials science and chemical physics (2002)