Reiner Lomoth group

Unraveling Bifurcating Pathways for CO and HCOOH Formation: Insights from Stopped-Flow FTIR Spectroscopy of a Second-Sphere Modified Mn Catalyst

Chattopadhyay, Samir; Barman, Sudip; Lomoth, Reiner; Hammarström, Leif

Part of Journal of the American Chemical Society, p. 22697-22704, 2025

• DOI for Unraveling Bifurcating Pathways for CO and HCOOH Formation: Insights from Stopped-Flow FTIR Spectroscopy of a Second-Sphere Modified Mn Catalyst
• Download full text (pdf) of Unraveling Bifurcating Pathways for CO and HCOOH Formation: Insights from Stopped-Flow FTIR Spectroscopy of a Second-Sphere Modified Mn Catalyst

Base-promoted homolytic aromatic substitution (BHAS) reactions and hydrodehalogenations driven by green light and an iron(III)-NHC photoredox catalyst

de Groot, Lisa H. M.; Garcia-Mateos, Clara; Johnson, Catherine E.; Hlynsson, Valtyr Freyr et al.

Part of Chemistry - A European Journal, 2025

• DOI for Base-promoted homolytic aromatic substitution (BHAS) reactions and hydrodehalogenations driven by green light and an iron(III)-NHC photoredox catalyst
• Download full text (pdf) of Base-promoted homolytic aromatic substitution (BHAS) reactions and hydrodehalogenations driven by green light and an iron(III)-NHC photoredox catalyst

Base-mediated alkynyl-cubane to Cu₈-alkynide cluster transformation

Gupta, Arvind Kumar; Fayet, Océane Y. O.; Tian, Lei; Berger, Raphael J. F. et al.

Part of Chemical Communications, p. 18673-18676, 2025

• DOI for Base-mediated alkynyl-cubane to Cu₈-alkynide cluster transformation
• Download full text (pdf) of Base-mediated alkynyl-cubane to Cu₈-alkynide cluster transformation

Shining light on the ferrous analogue: Excited state dynamics of an Fe(II) hexa-carbene scorpionate complex

Johnson, Catherine Ellen; Deegbey, Mawuli; Ilic, Aleksandra; Kaul, Nidhi et al.

Part of Dalton Transactions, p. 3586-3590, 2025

• DOI for Shining light on the ferrous analogue: Excited state dynamics of an Fe(II) hexa-carbene scorpionate complex
• Download full text (pdf) of Shining light on the ferrous analogue: Excited state dynamics of an Fe(II) hexa-carbene scorpionate complex

Tuning the ²LMCT Deactivation of Cyclometalated Iron Carbene Complexes with Electronic Substituent Effects

Mishra, Abhishek; Sharma, Kumkum; Johnson, Catherine E.; Fosu, Emmanuel Adu et al.

Part of Chemistry - A European Journal, 2025

• DOI for Tuning the ²LMCT Deactivation of Cyclometalated Iron Carbene Complexes with Electronic Substituent Effects
• Download full text (pdf) of Tuning the ²LMCT Deactivation of Cyclometalated Iron Carbene Complexes with Electronic Substituent Effects

Iron N-Heterocyclic Carbene Photoactive Complexes with Rigid Phenylethynyl Substituents as Ligand π-System Extensions

Persson, Samuel; Kumar Koninti, Raj; Barakat, Mariam; Mishra, Abhishek et al.

Part of Inorganic Chemistry, p. 12120-12131, 2025

• DOI for Iron N-Heterocyclic Carbene Photoactive Complexes with Rigid Phenylethynyl Substituents as Ligand π-System Extensions
• Download full text (pdf) of Iron N-Heterocyclic Carbene Photoactive Complexes with Rigid Phenylethynyl Substituents as Ligand π-System Extensions

Direct Detection of Key Intermediates during the Product Release in Rhenium Bipyridine-Catalyzed CO₂ Reduction Reaction

Chattopadhyay, Samir; Cheah, Mun Hon; Lomoth, Reiner; Hammarström, Leif

Part of ACS Catalysis, p. 16324-16334, 2024

• DOI for Direct Detection of Key Intermediates during the Product Release in Rhenium Bipyridine-Catalyzed CO₂ Reduction Reaction
• Download full text (pdf) of Direct Detection of Key Intermediates during the Product Release in Rhenium Bipyridine-Catalyzed CO₂ Reduction Reaction

Introducing Phosphorus into the Overcrowded Thiele's hydrocarbon Family: Unveiling Contorted Main Group Diradicaloids with Dynamic Redox Behavior

Deka, Rajesh; Asif Ansari, Mohd; Chattopadhyay, Samir; Lomoth, Reiner et al.

Part of Angewandte Chemie International Edition, 2024

• DOI for Introducing Phosphorus into the Overcrowded Thiele's hydrocarbon Family: Unveiling Contorted Main Group Diradicaloids with Dynamic Redox Behavior
• Download full text (pdf) of Introducing Phosphorus into the Overcrowded Thiele's hydrocarbon Family: Unveiling Contorted Main Group Diradicaloids with Dynamic Redox Behavior

Aminomethylations of electron-deficient compounds: bringing iron photoredox catalysis into play

Ilic, Aleksandra; Strücker, Benjamin R.; Johnson, Catherine E.; Hainz, Simon et al.

Part of Chemical Science, p. 12077-12085, 2024

• DOI for Aminomethylations of electron-deficient compounds: bringing iron photoredox catalysis into play
• Download full text (pdf) of Aminomethylations of electron-deficient compounds: bringing iron photoredox catalysis into play

How Rigidity and Conjugation of Bidentate Ligands Affect the Geometry and Photophysics of Iron N-Heterocyclic Complexes: A Comparative Study

Prakash, Om; Chabera, Pavel; Kaul, Nidhi; Hlynsson, Valtýr F. et al.

Part of Inorganic Chemistry, p. 4461-4473, 2024

• DOI for How Rigidity and Conjugation of Bidentate Ligands Affect the Geometry and Photophysics of Iron N-Heterocyclic Complexes: A Comparative Study
• Download full text (pdf) of How Rigidity and Conjugation of Bidentate Ligands Affect the Geometry and Photophysics of Iron N-Heterocyclic Complexes: A Comparative Study

Tailoring the Photophysical Properties of a Homoleptic Iron(II) Tetra N-Heterocyclic Carbene Complex by Attaching an Imidazolium Group to the (C^∧N^∧C) Pincer Ligand-A Comparative Study

Prakash, Om; Lindh, Linnea; Gupta, Arvind Kumar; Hoang Hai, Yen Tran et al.

Part of Inorganic Chemistry, p. 2909-2918, 2024

• DOI for Tailoring the Photophysical Properties of a Homoleptic Iron(II) Tetra N-Heterocyclic Carbene Complex by Attaching an Imidazolium Group to the (C^∧N^∧C) Pincer Ligand-A Comparative Study
• Download full text (pdf) of Tailoring the Photophysical Properties of a Homoleptic Iron(II) Tetra N-Heterocyclic Carbene Complex by Attaching an Imidazolium Group to the (C^∧N^∧C) Pincer Ligand-A Comparative Study

Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands: a case of dual emission revisited

Johnson, Catherine; Schwarz, Jesper; Deegbey, Mawuli; Prakash, Om et al.

Part of Chemical Science, p. 10129-10139, 2023

• DOI for Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands: a case of dual emission revisited
• Download full text (pdf) of Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands: a case of dual emission revisited

High-Efficiency Photoinduced Charge Separation in Fe(III)carbene Thin Films

Zhang, Minli; Johnson, Catherine; Ilic, Aleksandra; Schwarz, Jesper et al.

Part of Journal of the American Chemical Society, p. 19171-19176, 2023

• DOI for High-Efficiency Photoinduced Charge Separation in Fe(III)carbene Thin Films
• Download full text (pdf) of High-Efficiency Photoinduced Charge Separation in Fe(III)carbene Thin Films

A Bidirectional Bioinspired [FeFe]-Hydrogenase Model

Ahmed, Md Estak; Nayek, Abhijit; Krizan, Alenka; Coutard, Nathan et al.

Part of Journal of the American Chemical Society, p. 3614-3625, 2022

• DOI for A Bidirectional Bioinspired [FeFe]-Hydrogenase Model

Photoredox catalysis via consecutive ²LMCT- and ³MLCT-excitation of an Fe(iii/ii)–N-heterocyclic carbene complex

Ilic, Aleksandra; Schwarz, Jesper; Johnson, Catherine; de Groot, Lisa H. M. et al.

Part of Chemical Science, p. 9165-9175, 2022

• DOI for Photoredox catalysis via consecutive ²LMCT- and ³MLCT-excitation of an Fe(iii/ii)–N-heterocyclic carbene complex
• Download full text (pdf) of Photoredox catalysis via consecutive ²LMCT- and ³MLCT-excitation of an Fe(iii/ii)–N-heterocyclic carbene complex

Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)-NHC Complexes with Long-Lived 2LMCT Excited States

Prakash, Om; Lindh, Linnea; Kaul, Nidhi; Rosemann, Nils W. et al.

Part of Inorganic Chemistry, p. 17515-17526, 2022

• DOI for Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)-NHC Complexes with Long-Lived 2LMCT Excited States
• Download full text (pdf) of Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)-NHC Complexes with Long-Lived 2LMCT Excited States

High turnover photocatalytic hydrogen formation with an Fe(iii) N-heterocyclic carbene photosensitiser

Schwarz, Jesper; Ilic, Aleksandra; Johnson, Catherine; Lomoth, Reiner et al.

Part of Chemical Communications, p. 5351-5354, 2022

• DOI for High turnover photocatalytic hydrogen formation with an Fe(iii) N-heterocyclic carbene photosensitiser

The Carbene Cannibal: Photoinduced Symmetry-Breaking Charge Separation in an Fe(III) N-Heterocyclic Carbene

Kaul, Nidhi; Lomoth, Reiner

Part of Journal of the American Chemical Society, p. 10816-10821, 2021

• DOI for The Carbene Cannibal: Photoinduced Symmetry-Breaking Charge Separation in an Fe(III) N-Heterocyclic Carbene
• Download full text (pdf) of The Carbene Cannibal: Photoinduced Symmetry-Breaking Charge Separation in an Fe(III) N-Heterocyclic Carbene

Dye-sensitized solar cells based on Fe N-heterocyclic carbene photosensitizers with improved rod-like push-pull functionality

Lindh, Linnea; Gordivska, Olga; Persson, Samuel; Michaels, Hannes et al.

Part of Chemical Science, p. 16035-16053, 2021

• DOI for Dye-sensitized solar cells based on Fe N-heterocyclic carbene photosensitizers with improved rod-like push-pull functionality

Using Surface Amide Couplings to Assemble Photocathodes for Solar Fuel Production Applications

Materna, Kelly L.; Lalaoui, Noémie; Laureanti, Joseph A.; Walsh, Aaron P. et al.

Part of ACS Applied Materials and Interfaces, p. 4501-4509, 2020

• DOI for Using Surface Amide Couplings to Assemble Photocathodes for Solar Fuel Production Applications

A Stable Homoleptic Organometallic Iron(IV) Complex

Prakash, Om; Chabera, Pavel; Rosemann, Nils W.; Huang, Ping et al.

Part of Chemistry - A European Journal, p. 12728-12732, 2020

• DOI for A Stable Homoleptic Organometallic Iron(IV) Complex
• Download full text (pdf) of A Stable Homoleptic Organometallic Iron(IV) Complex

Metal vs. ligand protonation and the alleged proton-shuttling role of the azadithiolate ligand in catalytic H-2 formation with FeFe hydrogenase model complexes

Aster, Alexander; Wang, Shihuai; Mirmohades, Mohammad; Esmieu, Charlène et al.

Part of Chemical Science, p. 5582-5588, 2019

• DOI for Metal vs. ligand protonation and the alleged proton-shuttling role of the azadithiolate ligand in catalytic H-2 formation with FeFe hydrogenase model complexes
• Download full text (pdf) of Metal vs. ligand protonation and the alleged proton-shuttling role of the azadithiolate ligand in catalytic H-2 formation with FeFe hydrogenase model complexes

Luminescence and reactivity of a charge-transfer excited iron complex with nanosecond lifetime

Kjmer, Kasper Skov; Kaul, Nidhi; Prakash, Om; Chabera, Pavel et al.

Part of Science, p. 249-253, 2019

• DOI for Luminescence and reactivity of a charge-transfer excited iron complex with nanosecond lifetime

Direct Spectroscopic Detection of Key Intermediates and Turnover Process in Catalytic H₂ Formation by a Biomimetic Diiron Catalyst

Wang, Shihuai; Pullen, Sonja; Weippert, Valentin; Liu, Tianfei et al.

Part of Chemistry - A European Journal, p. 11135-11140, 2019

• DOI for Direct Spectroscopic Detection of Key Intermediates and Turnover Process in Catalytic H₂ Formation by a Biomimetic Diiron Catalyst

Fe-II Hexa N-Heterocyclic Carbene Complex with a 528 ps Metal-to-Ligand Charge-Transfer Excited-State Lifetime

Chabera, Pavel; Kjaer, Kasper S.; Prakash, Om; Honarfar, Alireza et al.

Part of The Journal of Physical Chemistry Letters, p. 459-463, 2018

• DOI for Fe-II Hexa N-Heterocyclic Carbene Complex with a 528 ps Metal-to-Ligand Charge-Transfer Excited-State Lifetime

Accelerating proton-coupled electron transfer of metal hydrides in catalyst model reactions

Liu, Tianfei; Guo, Meiyuan; Orthaber, Andreas; Lomoth, Reiner et al.

Part of Nature Chemistry, p. 881-887, 2018

• DOI for Accelerating proton-coupled electron transfer of metal hydrides in catalyst model reactions
• Download full text (pdf) of Accelerating proton-coupled electron transfer of metal hydrides in catalyst model reactions

Probing the elementary steps of PCET catalysis

Lomoth, Reiner; Liu, Tianfei; Wang, Shihuai; Ott, Sascha et al.

Part of Abstracts of Papers of the American Chemical Society, 2018

Structural and Kinetic Studies of Intermediates of a Biomimetic Diiron Proton-Reduction Catalyst

Wang, Shihuai; Aster, Alexander; Lomoth, Reiner; Hammarström, Leif

Part of Inorganic Chemistry, p. 768-776, 2018

• DOI for Structural and Kinetic Studies of Intermediates of a Biomimetic Diiron Proton-Reduction Catalyst

A low-spin Fe(III) complex with 100-ps ligand-to-metal charge transfer photoluminescence

Chabera, Pavel; Liu, Yizhu; Prakash, Om; Thyrhaug, Erling et al.

Part of Nature, p. 695-+, 2017

• DOI for A low-spin Fe(III) complex with 100-ps ligand-to-metal charge transfer photoluminescence

Photochemistry of iron(III) carbenes

Fredin, Lisa; Chabera, Pavel; Lomoth, Reiner; Sundstrom, Villy et al.

Part of Abstracts of Papers of the American Chemical Society, 2017

Capturing intermediates of molecular solar fuels catalysts by time-resolved mid-IR spectroscopy

Hammarström, Leif; Lomoth, Reiner; Ott, Sascha

Part of Abstracts of Papers of the American Chemical Society, 2017

Evaluation of two- and three-dimensional electrode platforms for the electrochemical characterization of organometallic catalysts incorporated in non-conducting metal-organic frameworks

Mijangos, Edgar; Roy, Souvik; Pullen, Sonja; Lomoth, Reiner et al.

Part of Dalton Transactions, p. 4907-4911, 2017

• DOI for Evaluation of two- and three-dimensional electrode platforms for the electrochemical characterization of organometallic catalysts incorporated in non-conducting metal-organic frameworks

Following [FeFe] Hydrogenase Active Site Intermediates by Time-Resolved Mid-IR Spectroscopy

Mirmohades, Mohammad; Adamska-Venkatesh, Agnieszka; Sommer, Constanze; Reijerse, Edward et al.

Part of The Journal of Physical Chemistry Letters, p. 3290-3293, 2016

• DOI for Following [FeFe] Hydrogenase Active Site Intermediates by Time-Resolved Mid-IR Spectroscopy
• Download full text (pdf) of Following [FeFe] Hydrogenase Active Site Intermediates by Time-Resolved Mid-IR Spectroscopy

Catalyst solvent interactions in a dinuclear Ru-based water oxidation catalyst

Shatskiy, Andrey; Lomoth, Reiner; Abdel-Magied, Ahmed F.; Rabten, Wangchuk et al.

Part of Dalton Transactions, p. 19024-19033, 2016

• DOI for Catalyst solvent interactions in a dinuclear Ru-based water oxidation catalyst
• Download full text (pdf) of Catalyst solvent interactions in a dinuclear Ru-based water oxidation catalyst

Elucidating the Ultrafast Dynamics of Photoinduced Charge Separation in Metalloporphyrin-Fullerene Dyads Across the Electromagnetic Spectrum

Zhang, J.; Papai, M.; Hirsch, A.; Jennings, G. et al.

Part of The Journal of Physical Chemistry C, p. 19537-19546, 2016

• DOI for Elucidating the Ultrafast Dynamics of Photoinduced Charge Separation in Metalloporphyrin-Fullerene Dyads Across the Electromagnetic Spectrum

Iron sensitizer converts light to electrons with 92% yield

Harlang, Tobias C. B.; Liu, Yizhu; Gordivska, Olga; Fredin, Lisa A. et al.

Part of Nature Chemistry, p. 883-889, 2015

• DOI for Iron sensitizer converts light to electrons with 92% yield

Surface modification of carbon and metal electrodes with bistable molecular redox switches by click and amide coupling

Jane, R. T.; Gaudemer, E.; Lomoth, Reiner

Part of Journal of Materials Chemistry C, p. 10023-10030, 2015

• DOI for Surface modification of carbon and metal electrodes with bistable molecular redox switches by click and amide coupling

Redox hysteresis on carbon electrodes covalently modified with a bistable ruthenium complex

Jane, Reuben T.; Lomoth, Reiner

Part of Journal of Materials Chemistry C, p. 6260-6265, 2015

• DOI for Redox hysteresis on carbon electrodes covalently modified with a bistable ruthenium complex

A Heteroleptic Ferrous Complex with Mesoionic Bis(1,2,3-triazol-5-ylidene) Ligands: Taming the MLCT Excited State of Iron(II)

Liu, Yizhu; Kjær, Kasper S.; Fredin, Lisa A.; Chábera, Pavel et al.

Part of Chemistry - A European Journal, p. 3628-3639, 2015

• DOI for A Heteroleptic Ferrous Complex with Mesoionic Bis(1,2,3-triazol-5-ylidene) Ligands: Taming the MLCT Excited State of Iron(II)

Sensitizer-Catalyst Assemblies for Water Oxidation

Wang, Lei; Mirmohades, Mohammad; Brown, Allison; Duan, Lele et al.

Part of Inorganic Chemistry, p. 2742-2751, 2015

• DOI for Sensitizer-Catalyst Assemblies for Water Oxidation

Redox Switching in Ethenyl- Bridged Bisphospholes

Arkhypchuk, Anna I.; Mijangos, Edgar; Lomoth, Reiner; Ott, Sascha

Part of Chemistry - A European Journal, p. 16083-16087, 2014

• DOI for Redox Switching in Ethenyl- Bridged Bisphospholes

Mechanistic investigations and detection of intermediates of molecular proton reduction catalysts

Hammarström, Leif; Brown, Allison; Mirmohades, Mohammad; Pullen, Sonja et al.

Part of Abstracts of Papers of the American Chemical Society, 2014

Direct Observation of Key Catalytic Intermediates in a Photoinduced Proton Reduction Cycle with a Diiron Carbonyl Complex

Mirmohades, Mohammad; Pullen, Sonja; Stein, Matthias; Maji, Somnath et al.

Part of Journal of the American Chemical Society, p. 17366-17369, 2014

• DOI for Direct Observation of Key Catalytic Intermediates in a Photoinduced Proton Reduction Cycle with a Diiron Carbonyl Complex

Pyrene–Azobenzene Dyads and Their Photochemistry

Nachtigall, Olaf; Lomoth, Reiner; Dahlstrand, Christian; Lundstedt, Anna et al.

Part of European Journal of Organic Chemistry, p. 966-972, 2014

• DOI for Pyrene–Azobenzene Dyads and Their Photochemistry

Toward Highlighting the Ultrafast Electron Transfer Dynamics at the Optically Dark Sites of Photocatalysts

Canton, Sophie E.; Zhang, Xiaoyi; Zhang, Jianxin; van Driel, Tim B. et al.

Part of The Journal of Physical Chemistry Letters, p. 1972-1976, 2013

• DOI for Toward Highlighting the Ultrafast Electron Transfer Dynamics at the Optically Dark Sites of Photocatalysts

Towards longer-lived metal-to-ligand charge transfer states of iron(II) complexes: an N-heterocyclic carbene approach

Liu, Yizhu; Harlang, Tobias; Canton, Sophie E.; Chabera, Pavel et al.

Part of Chemical Communications, p. 6412-6414, 2013

• DOI for Towards longer-lived metal-to-ligand charge transfer states of iron(II) complexes: an N-heterocyclic carbene approach

Redox-Stimulated Motion and Bistability in Metal Complexes and Organometallic Compounds

Lomoth, Reiner

Part of Antioxidants and Redox Signaling, p. 1803-1814, 2013

• DOI for Redox-Stimulated Motion and Bistability in Metal Complexes and Organometallic Compounds

Tuning the Electronics of Bis(tridentate)ruthenium(II) Complexes with Long-Lived Excited States: Modifications to the Ligand Skeleton beyond Classical Electron Donor or Electron Withdrawing Group Decorations

Parada, Giovanny A.; Fredin, Lisa A.; Santoni, Marie-Pierre; Jaeger, Michael et al.

Part of Inorganic Chemistry, p. 5128-5137, 2013

• DOI for Tuning the Electronics of Bis(tridentate)ruthenium(II) Complexes with Long-Lived Excited States: Modifications to the Ligand Skeleton beyond Classical Electron Donor or Electron Withdrawing Group Decorations

Voltammetric and spectroscopic characterization of early intermediates in the Co(II)-polypyridyl-catalyzed reduction of water

Singh, Wangkheimayum Marjit; Mirmohades, Mohammad; Jane, Reuben T.; White, Travis A. et al.

Part of Chemical Communications, p. 8638-8640, 2013

• DOI for Voltammetric and spectroscopic characterization of early intermediates in the Co(II)-polypyridyl-catalyzed reduction of water

Synthesis, Structure, and Electronic Properties of RuN(6) Dinuclear Ru-Hbpp Complexes

Roeser, Stephan; Ertem, Mehmed Z.; Cady, Clyde; Lomoth, Rainer et al.

Part of Inorganic Chemistry, p. 320-327, 2012

• DOI for Synthesis, Structure, and Electronic Properties of RuN(6) Dinuclear Ru-Hbpp Complexes