Reiner Lomoth group

How Rigidity and Conjugation of Bidentate Ligands Affect the Geometry and Photophysics of Iron N-Heterocyclic Complexes: A Comparative Study

Prakash, Om; Chabera, Pavel; Kaul, Nidhi; Hlynsson, Valtýr F. et al.

Part of Inorganic Chemistry, p. 4461-4473, 2024

• DOI for How Rigidity and Conjugation of Bidentate Ligands Affect the Geometry and Photophysics of Iron N-Heterocyclic Complexes: A Comparative Study
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Tailoring the Photophysical Properties of a Homoleptic Iron(II) Tetra N-Heterocyclic Carbene Complex by Attaching an Imidazolium Group to the (C^∧N^∧C) Pincer Ligand-A Comparative Study

Prakash, Om; Lindh, Linnea; Gupta, Arvind Kumar; Hoang Hai, Yen Tran et al.

Part of Inorganic Chemistry, p. 2909-2918, 2024

• DOI for Tailoring the Photophysical Properties of a Homoleptic Iron(II) Tetra N-Heterocyclic Carbene Complex by Attaching an Imidazolium Group to the (C^∧N^∧C) Pincer Ligand-A Comparative Study
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Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands: a case of dual emission revisited

Johnson, Catherine; Schwarz, Jesper; Deegbey, Mawuli; Prakash, Om et al.

Part of Chemical Science, p. 10129-10139, 2023

• DOI for Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands: a case of dual emission revisited
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High-Efficiency Photoinduced Charge Separation in Fe(III)carbene Thin Films

Zhang, Minli; Johnson, Catherine; Ilic, Aleksandra; Schwarz, Jesper et al.

Part of Journal of the American Chemical Society, p. 19171-19176, 2023

• DOI for High-Efficiency Photoinduced Charge Separation in Fe(III)carbene Thin Films
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A Bidirectional Bioinspired [FeFe]-Hydrogenase Model

Ahmed, Md Estak; Nayek, Abhijit; Krizan, Alenka; Coutard, Nathan et al.

Part of Journal of the American Chemical Society, p. 3614-3625, 2022

• DOI for A Bidirectional Bioinspired [FeFe]-Hydrogenase Model

Photoredox catalysis via consecutive ²LMCT- and ³MLCT-excitation of an Fe(iii/ii)–N-heterocyclic carbene complex

Ilic, Aleksandra; Schwarz, Jesper; Johnson, Catherine; de Groot, Lisa H. M. et al.

Part of Chemical Science, p. 9165-9175, 2022

• DOI for Photoredox catalysis via consecutive ²LMCT- and ³MLCT-excitation of an Fe(iii/ii)–N-heterocyclic carbene complex
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Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)-NHC Complexes with Long-Lived 2LMCT Excited States

Prakash, Om; Lindh, Linnea; Kaul, Nidhi; Rosemann, Nils W. et al.

Part of Inorganic Chemistry, p. 17515-17526, 2022

• DOI for Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)-NHC Complexes with Long-Lived 2LMCT Excited States
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High turnover photocatalytic hydrogen formation with an Fe(iii) N-heterocyclic carbene photosensitiser

Schwarz, Jesper; Ilic, Aleksandra; Johnson, Catherine; Lomoth, Reiner et al.

Part of Chemical Communications, p. 5351-5354, 2022

• DOI for High turnover photocatalytic hydrogen formation with an Fe(iii) N-heterocyclic carbene photosensitiser

The Carbene Cannibal: Photoinduced Symmetry-Breaking Charge Separation in an Fe(III) N-Heterocyclic Carbene

Kaul, Nidhi; Lomoth, Reiner

Part of Journal of the American Chemical Society, p. 10816-10821, 2021

• DOI for The Carbene Cannibal: Photoinduced Symmetry-Breaking Charge Separation in an Fe(III) N-Heterocyclic Carbene
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Dye-sensitized solar cells based on Fe N-heterocyclic carbene photosensitizers with improved rod-like push-pull functionality

Lindh, Linnea; Gordivska, Olga; Persson, Samuel; Michaels, Hannes et al.

Part of Chemical Science, p. 16035-16053, 2021

• DOI for Dye-sensitized solar cells based on Fe N-heterocyclic carbene photosensitizers with improved rod-like push-pull functionality

Using Surface Amide Couplings to Assemble Photocathodes for Solar Fuel Production Applications

Materna, Kelly L.; Lalaoui, Noémie; Laureanti, Joseph A.; Walsh, Aaron P. et al.

Part of ACS Applied Materials and Interfaces, p. 4501-4509, 2020

• DOI for Using Surface Amide Couplings to Assemble Photocathodes for Solar Fuel Production Applications

A Stable Homoleptic Organometallic Iron(IV) Complex

Prakash, Om; Chabera, Pavel; Rosemann, Nils W.; Huang, Ping et al.

Part of Chemistry - A European Journal, p. 12728-12732, 2020

• DOI for A Stable Homoleptic Organometallic Iron(IV) Complex
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Metal vs. ligand protonation and the alleged proton-shuttling role of the azadithiolate ligand in catalytic H-2 formation with FeFe hydrogenase model complexes

Aster, Alexander; Wang, Shihuai; Mirmohades, Mohammad; Esmieu, Charlène et al.

Part of Chemical Science, p. 5582-5588, 2019

• DOI for Metal vs. ligand protonation and the alleged proton-shuttling role of the azadithiolate ligand in catalytic H-2 formation with FeFe hydrogenase model complexes
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Luminescence and reactivity of a charge-transfer excited iron complex with nanosecond lifetime

Kjmer, Kasper Skov; Kaul, Nidhi; Prakash, Om; Chabera, Pavel et al.

Part of Science, p. 249-253, 2019

• DOI for Luminescence and reactivity of a charge-transfer excited iron complex with nanosecond lifetime

Direct Spectroscopic Detection of Key Intermediates and Turnover Process in Catalytic H₂ Formation by a Biomimetic Diiron Catalyst

Wang, Shihuai; Pullen, Sonja; Weippert, Valentin; Liu, Tianfei et al.

Part of Chemistry - A European Journal, p. 11135-11140, 2019

• DOI for Direct Spectroscopic Detection of Key Intermediates and Turnover Process in Catalytic H₂ Formation by a Biomimetic Diiron Catalyst

Fe-II Hexa N-Heterocyclic Carbene Complex with a 528 ps Metal-to-Ligand Charge-Transfer Excited-State Lifetime

Chabera, Pavel; Kjaer, Kasper S.; Prakash, Om; Honarfar, Alireza et al.

Part of The Journal of Physical Chemistry Letters, p. 459-463, 2018

• DOI for Fe-II Hexa N-Heterocyclic Carbene Complex with a 528 ps Metal-to-Ligand Charge-Transfer Excited-State Lifetime

Accelerating proton-coupled electron transfer of metal hydrides in catalyst model reactions

Liu, Tianfei; Guo, Meiyuan; Orthaber, Andreas; Lomoth, Reiner et al.

Part of Nature Chemistry, p. 881-887, 2018

• DOI for Accelerating proton-coupled electron transfer of metal hydrides in catalyst model reactions
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Structural and Kinetic Studies of Intermediates of a Biomimetic Diiron Proton-Reduction Catalyst

Wang, Shihuai; Aster, Alexander; Lomoth, Reiner; Hammarström, Leif

Part of Inorganic Chemistry, p. 768-776, 2018

• DOI for Structural and Kinetic Studies of Intermediates of a Biomimetic Diiron Proton-Reduction Catalyst

A low-spin Fe(III) complex with 100-ps ligand-to-metal charge transfer photoluminescence

Chabera, Pavel; Liu, Yizhu; Prakash, Om; Thyrhaug, Erling et al.

Part of Nature, p. 695-+, 2017

• DOI for A low-spin Fe(III) complex with 100-ps ligand-to-metal charge transfer photoluminescence

Evaluation of two- and three-dimensional electrode platforms for the electrochemical characterization of organometallic catalysts incorporated in non-conducting metal-organic frameworks

Mijangos, Edgar; Roy, Souvik; Pullen, Sonja; Lomoth, Reiner et al.

Part of Dalton Transactions, p. 4907-4911, 2017

• DOI for Evaluation of two- and three-dimensional electrode platforms for the electrochemical characterization of organometallic catalysts incorporated in non-conducting metal-organic frameworks

Following [FeFe] Hydrogenase Active Site Intermediates by Time-Resolved Mid-IR Spectroscopy

Mirmohades, Mohammad; Adamska-Venkatesh, Agnieszka; Sommer, Constanze; Reijerse, Edward et al.

Part of The Journal of Physical Chemistry Letters, p. 3290-3293, 2016

• DOI for Following [FeFe] Hydrogenase Active Site Intermediates by Time-Resolved Mid-IR Spectroscopy
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Catalyst solvent interactions in a dinuclear Ru-based water oxidation catalyst

Shatskiy, Andrey; Lomoth, Reiner; Abdel-Magied, Ahmed F.; Rabten, Wangchuk et al.

Part of Dalton Transactions, p. 19024-19033, 2016

• DOI for Catalyst solvent interactions in a dinuclear Ru-based water oxidation catalyst
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Elucidating the Ultrafast Dynamics of Photoinduced Charge Separation in Metalloporphyrin-Fullerene Dyads Across the Electromagnetic Spectrum

Zhang, J.; Papai, M.; Hirsch, A.; Jennings, G. et al.

Part of The Journal of Physical Chemistry C, p. 19537-19546, 2016

• DOI for Elucidating the Ultrafast Dynamics of Photoinduced Charge Separation in Metalloporphyrin-Fullerene Dyads Across the Electromagnetic Spectrum

Iron sensitizer converts light to electrons with 92% yield

Harlang, Tobias C. B.; Liu, Yizhu; Gordivska, Olga; Fredin, Lisa A. et al.

Part of Nature Chemistry, p. 883-889, 2015

• DOI for Iron sensitizer converts light to electrons with 92% yield

Surface modification of carbon and metal electrodes with bistable molecular redox switches by click and amide coupling

Jane, R. T.; Gaudemer, E.; Lomoth, Reiner

Part of Journal of Materials Chemistry C, p. 10023-10030, 2015

• DOI for Surface modification of carbon and metal electrodes with bistable molecular redox switches by click and amide coupling

Redox hysteresis on carbon electrodes covalently modified with a bistable ruthenium complex

Jane, Reuben T.; Lomoth, Reiner

Part of Journal of Materials Chemistry C, p. 6260-6265, 2015

• DOI for Redox hysteresis on carbon electrodes covalently modified with a bistable ruthenium complex

A Heteroleptic Ferrous Complex with Mesoionic Bis(1,2,3-triazol-5-ylidene) Ligands: Taming the MLCT Excited State of Iron(II)

Liu, Yizhu; Kjær, Kasper S.; Fredin, Lisa A.; Chábera, Pavel et al.

Part of Chemistry - A European Journal, p. 3628-3639, 2015

• DOI for A Heteroleptic Ferrous Complex with Mesoionic Bis(1,2,3-triazol-5-ylidene) Ligands: Taming the MLCT Excited State of Iron(II)

Sensitizer-Catalyst Assemblies for Water Oxidation

Wang, Lei; Mirmohades, Mohammad; Brown, Allison; Duan, Lele et al.

Part of Inorganic Chemistry, p. 2742-2751, 2015

• DOI for Sensitizer-Catalyst Assemblies for Water Oxidation

Redox Switching in Ethenyl- Bridged Bisphospholes

Arkhypchuk, Anna I.; Mijangos, Edgar; Lomoth, Reiner; Ott, Sascha

Part of Chemistry - A European Journal, p. 16083-16087, 2014

• DOI for Redox Switching in Ethenyl- Bridged Bisphospholes

Direct Observation of Key Catalytic Intermediates in a Photoinduced Proton Reduction Cycle with a Diiron Carbonyl Complex

Mirmohades, Mohammad; Pullen, Sonja; Stein, Matthias; Maji, Somnath et al.

Part of Journal of the American Chemical Society, p. 17366-17369, 2014

• DOI for Direct Observation of Key Catalytic Intermediates in a Photoinduced Proton Reduction Cycle with a Diiron Carbonyl Complex

Pyrene–Azobenzene Dyads and Their Photochemistry

Nachtigall, Olaf; Lomoth, Reiner; Dahlstrand, Christian; Lundstedt, Anna et al.

Part of European Journal of Organic Chemistry, p. 966-972, 2014

• DOI for Pyrene–Azobenzene Dyads and Their Photochemistry

Toward Highlighting the Ultrafast Electron Transfer Dynamics at the Optically Dark Sites of Photocatalysts

Canton, Sophie E.; Zhang, Xiaoyi; Zhang, Jianxin; van Driel, Tim B. et al.

Part of The Journal of Physical Chemistry Letters, p. 1972-1976, 2013

• DOI for Toward Highlighting the Ultrafast Electron Transfer Dynamics at the Optically Dark Sites of Photocatalysts

Towards longer-lived metal-to-ligand charge transfer states of iron(II) complexes: an N-heterocyclic carbene approach

Liu, Yizhu; Harlang, Tobias; Canton, Sophie E.; Chabera, Pavel et al.

Part of Chemical Communications, p. 6412-6414, 2013

• DOI for Towards longer-lived metal-to-ligand charge transfer states of iron(II) complexes: an N-heterocyclic carbene approach

Redox-Stimulated Motion and Bistability in Metal Complexes and Organometallic Compounds

Lomoth, Reiner

Part of Antioxidants and Redox Signaling, p. 1803-1814, 2013

• DOI for Redox-Stimulated Motion and Bistability in Metal Complexes and Organometallic Compounds

Tuning the Electronics of Bis(tridentate)ruthenium(II) Complexes with Long-Lived Excited States: Modifications to the Ligand Skeleton beyond Classical Electron Donor or Electron Withdrawing Group Decorations

Parada, Giovanny A.; Fredin, Lisa A.; Santoni, Marie-Pierre; Jaeger, Michael et al.

Part of Inorganic Chemistry, p. 5128-5137, 2013

• DOI for Tuning the Electronics of Bis(tridentate)ruthenium(II) Complexes with Long-Lived Excited States: Modifications to the Ligand Skeleton beyond Classical Electron Donor or Electron Withdrawing Group Decorations

Voltammetric and spectroscopic characterization of early intermediates in the Co(II)-polypyridyl-catalyzed reduction of water

Singh, Wangkheimayum Marjit; Mirmohades, Mohammad; Jane, Reuben T.; White, Travis A. et al.

Part of Chemical Communications, p. 8638-8640, 2013

• DOI for Voltammetric and spectroscopic characterization of early intermediates in the Co(II)-polypyridyl-catalyzed reduction of water

Synthesis, Structure, and Electronic Properties of RuN(6) Dinuclear Ru-Hbpp Complexes

Roeser, Stephan; Ertem, Mehmed Z.; Cady, Clyde; Lomoth, Rainer et al.

Part of Inorganic Chemistry, p. 320-327, 2012

• DOI for Synthesis, Structure, and Electronic Properties of RuN(6) Dinuclear Ru-Hbpp Complexes

Pentacoordinate iron complexes as functional models of the distal iron in [FeFe] hydrogenases

Beyler, Maryline; Ezzaher, Salah; Karnahl, Michael; Santoni, Marie-Pierre et al.

Part of Chemical Communications, p. 11662-11664, 2011

• DOI for Pentacoordinate iron complexes as functional models of the distal iron in [FeFe] hydrogenases

Comparing the Reactivity of Benzenedithiolate- versus Alkyldithiolate-Bridged Fe₂(CO)₆ Complexes with Competing Ligands

Streich, Daniel; Karnahl, Michael; Astuti, Yeni; Cady, Clyde W. et al.

Part of European Journal of Inorganic Chemistry, p. 1106-1111, 2011

• DOI for Comparing the Reactivity of Benzenedithiolate- versus Alkyldithiolate-Bridged Fe₂(CO)₆ Complexes with Competing Ligands

Spectroscopically characterized intermediates of catalytic H₂ formation by [FeFe] hydrogenase models

Tschierlei, Stefanie; Ott, Sascha; Lomoth, Reiner

Part of Energy & Environmental Science, p. 2340-2352, 2011

• DOI for Spectroscopically characterized intermediates of catalytic H₂ formation by [FeFe] hydrogenase models

Catalytic Hydrogen Evolution from Mononuclear Iron(II) Carbonyl Complexes as Minimal Functional Models of the [FeFe] Hydrogenase Active Site

Kaur-Ghumaan, Sandeep; Schwartz, Lennart; Lomoth, Reiner; Stein, Matthias et al.

Part of Angewandte Chemie International Edition, p. 8033-8036, 2010

• DOI for Catalytic Hydrogen Evolution from Mononuclear Iron(II) Carbonyl Complexes as Minimal Functional Models of the [FeFe] Hydrogenase Active Site

High-Turnover Photochemical Hydrogen Production Catalyzed by a Model Complex of the [FeFe]-Hydrogenase Active Site

Streich, Daniel; Astuti, Yeni; Orlandi, Michele; Schwartz, Lennart et al.

Part of Chemistry - A European Journal, p. 60-63, 2010

• DOI for High-Turnover Photochemical Hydrogen Production Catalyzed by a Model Complex of the [FeFe]-Hydrogenase Active Site

Bistable Molecular Switches Based on Linkage Isomerization in Ruthenium Polypyridyl Complexes with a Ligand-Bound Ambidentate Motif

Johansson, Olof; Johannissen, Linus O.; Lomoth, Reiner

Part of Chemistry - A European Journal, p. 1195-1204, 2009

• DOI for Bistable Molecular Switches Based on Linkage Isomerization in Ruthenium Polypyridyl Complexes with a Ligand-Bound Ambidentate Motif

Introducing a dark reaction to photochemistry: photocatalytic hydrogen from [FeFe] hydrogenase active site model complexes

Lomoth, Reiner; Ott, Sascha

Part of Dalton Transactions, p. 9952-9959, 2009

• DOI for Introducing a dark reaction to photochemistry: photocatalytic hydrogen from [FeFe] hydrogenase active site model complexes

Biomimetic and Microbial Approaches to Solar Fuel Generation

Magnuson, Ann; Anderlund, Magnus; Johansson, Olof; Lindblad, Peter et al.

Part of Accounts of Chemical Research, p. 1899-1909, 2009

• DOI for Biomimetic and Microbial Approaches to Solar Fuel Generation

(I,0) Mixed-Valence State of a Diiron Complex with Pertinence to the [FeFe]-Hydrogenase Active Site: An IR, EPR, and Computational Study

Singh, Pradyumna S.; Rudbeck, Hans Christian; Huang, Ping; Ezzaher, Salah et al.

Part of Inorganic Chemistry, p. 10883-10885, 2009

• DOI for (I,0) Mixed-Valence State of a Diiron Complex with Pertinence to the [FeFe]-Hydrogenase Active Site: An IR, EPR, and Computational Study

A surface-attached Ru complex operating as a rapid bistable molecular switch

Tsekouras, George; Johansson, Olof; Lomoth, Reiner

Part of Chemical Communications, p. 3425-3427, 2009

• DOI for A surface-attached Ru complex operating as a rapid bistable molecular switch

Pd-catalyzed diarylation of aniline: a way to a non-linear bis(terpyridyl) ligand providing increased electronic communication

Johansson, Olof; Eriksson, Lars; Lomoth, Reiner

Part of Dalton Transactions, p. 3649-3651, 2008

• DOI for Pd-catalyzed diarylation of aniline: a way to a non-linear bis(terpyridyl) ligand providing increased electronic communication

Molecular hysteresis in a rigid dinuclear ruthenium polypyridyl complex incorporating a ligand-bound ambidentate motif

Johansson, Olof; Lomoth, Reiner

Part of Inorganic Chemistry, p. 5531-5533, 2008

• DOI for Molecular hysteresis in a rigid dinuclear ruthenium polypyridyl complex incorporating a ligand-bound ambidentate motif

The role of colloid formation in the photoinduced H₂ production with a Ru^II-Pd^II supramolecular complex: A study by GC, XPS, and TEM

Lei, Pengxiang; Hedlund, Maria; Lomoth, Reiner; Rensmo, Håkan et al.

Part of Journal of the American Chemical Society, p. 26-27, 2008

• DOI for The role of colloid formation in the photoinduced H₂ production with a Ru^II-Pd^II supramolecular complex: A study by GC, XPS, and TEM