Victor Gray group

Exciting Molecules
Our research
When a molecule or material absorbs light it becomes excited and we study how these excited states behave by using a range of spectroscopic techniques such as transient absorption and fluorescence spectroscopy. An excited state can for example be transferred to a new molecule (energy transfer) or transfer an electron/hole to generate a charge separated state. Other fascinating possibilities are the splitting (fission) of an excited state to two low energy states, or the fusion of two states to one higher energy state.
Excited state dynamics are central in many applications ranging from solar energy harvesting and photocatalysis to light emission devices and imaging. Understanding the excited state dynamics helps us develop new better materials for these applications. We also often make the molecules that we want to study to be able to design them for specific applications.
Our research topics
Two topics of particular interest in the group are:
Singlet fission
Singlet fission is a process in some organic molecules that splits a singlet excited state into two triplet excited states on neighbouring molecules. In this way the photon energy can be split in two. By incorporating singlet fission with solar cells, the solar cell efficiency could be significantly enhanced by using the high energy part of the solar spectrum more efficiently.
Photon Upconversion
The process where two low energy photons are combined to generate one photon of higher energy is called photon upconversion. Photon upconversion can be achieve through a process known as triplet-triplet annihilation (TTA), which is the reverse of singlet fission. Here two triplet excited states are fused to form one high energy singlet state. With photon upconversion, light that otherwise is not absorbed by a device is made available, with the possibility of enhancing solar cell and photocatalytic device performance.
More information
If you want to know more about the research within the Gray Group, see the group's external website for more information.
Gruppmedlemmar
Publications
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Remotely Tuned Triplet Transfer via Ligand Proximity in Quantum Dot-Organic Spectral Converters
Part of ACS Nano, p. 9996-10011, 2026
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Part of The Journal of Physical Chemistry C, p. 2616-2624, 2026
- DOI for Key Roles of Aliphatic Ligands over PbS Quantum Dots for Efficient Triplet Energy Transfer in a Hybrid TES-ADT/PbS System for Triplet-Triplet Annihilation Photon Upconversion
- Download full text (pdf) of Key Roles of Aliphatic Ligands over PbS Quantum Dots for Efficient Triplet Energy Transfer in a Hybrid TES-ADT/PbS System for Triplet-Triplet Annihilation Photon Upconversion
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Part of Journal of the American Chemical Society, p. 40214-40224, 2025
- DOI for Improving Triplet-Triplet Annihilation Upconversion Output by a Triplet Mediator Approach: Mechanistic Insights on Homo and Hetero-Annihilation in Three-Component Systems
- Download full text (pdf) of Improving Triplet-Triplet Annihilation Upconversion Output by a Triplet Mediator Approach: Mechanistic Insights on Homo and Hetero-Annihilation in Three-Component Systems
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Part of Journal of the American Chemical Society, p. 7763-7770, 2024
- DOI for Ligand-Directed Self-Assembly of Organic-Semiconductor/Quantum-Dot Blend Films Enables Efficient Triplet Exciton-Photon Conversion
- Download full text (pdf) of Ligand-Directed Self-Assembly of Organic-Semiconductor/Quantum-Dot Blend Films Enables Efficient Triplet Exciton-Photon Conversion
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Part of Journal of the American Chemical Society, p. 35146-35154, 2024
- DOI for Synchronized Photoluminescence and Electrical Mobility Enhancement in 2D WS2 through Sequence-Specific Chemical Passivation
- Download full text (pdf) of Synchronized Photoluminescence and Electrical Mobility Enhancement in 2D WS2 through Sequence-Specific Chemical Passivation
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Part of Energy & Environmental Science, p. 4982-5016, 2022
- DOI for Recent advances in triplet-triplet annihilation upconversion and singlet fission, towards solar energy applications
- Download full text (pdf) of Recent advances in triplet-triplet annihilation upconversion and singlet fission, towards solar energy applications
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Deoxyribonucleic Acid Encoded and Size-Defined π-Stacking of Perylene Diimides
Part of Journal of the American Chemical Society, p. 368-376, 2022
- DOI for Deoxyribonucleic Acid Encoded and Size-Defined π-Stacking of Perylene Diimides
- Download full text (pdf) of Deoxyribonucleic Acid Encoded and Size-Defined π-Stacking of Perylene Diimides
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Triplet transfer from PbS quantum dots to tetracene ligands: is faster always better?
Part of Journal of Materials Chemistry C, p. 16321-16329, 2022
- DOI for Triplet transfer from PbS quantum dots to tetracene ligands: is faster always better?
- Download full text (pdf) of Triplet transfer from PbS quantum dots to tetracene ligands: is faster always better?
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Insights into the Structure and Self-Assembly of Organic-Semiconductor/Quantum-Dot Blends
Part of Advanced Functional Materials, 2022
- DOI for Insights into the Structure and Self-Assembly of Organic-Semiconductor/Quantum-Dot Blends
- Download full text (pdf) of Insights into the Structure and Self-Assembly of Organic-Semiconductor/Quantum-Dot Blends
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Part of Journal of Materials Chemistry C, p. 11192-11198, 2022
- DOI for Linking microscale morphologies to localised performance in singlet fission quantum dot photon multiplier thin films
- Download full text (pdf) of Linking microscale morphologies to localised performance in singlet fission quantum dot photon multiplier thin films
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Suppressing aggregation induced quenching in anthracene based conjugated polymers
Part of Polymer Chemistry, p. 1830-1836, 2021
- DOI for Suppressing aggregation induced quenching in anthracene based conjugated polymers
- Download full text (pdf) of Suppressing aggregation induced quenching in anthracene based conjugated polymers
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Organic-quantum dot hybrid interfaces and their role in photon fission/fusion applications
Part of Chemical Physics Reviews, 2021
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Part of Journal of the American Chemical Society, p. 5745-5754, 2021
- DOI for Diphenylanthracene Dimers for Triplet-Triplet Annihilation Photon Upconversion: Mechanistic Insights for Intramolecular Pathways and the Importance of Molecular Geometry
- Download full text (pdf) of Diphenylanthracene Dimers for Triplet-Triplet Annihilation Photon Upconversion: Mechanistic Insights for Intramolecular Pathways and the Importance of Molecular Geometry
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Part of ACS Nano, p. 4224-4234, 2020
- DOI for Direct vs Delayed Triplet Energy Transfer from Organic Semiconductors to Quantum Dots and Implications for Luminescent Harvesting of Triplet Excitons
- Download full text (pdf) of Direct vs Delayed Triplet Energy Transfer from Organic Semiconductors to Quantum Dots and Implications for Luminescent Harvesting of Triplet Excitons
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Part of The Journal of Physical Chemistry Letters, p. 7239-7244, 2020
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Evolution from Tunneling to Hopping Mediated Triplet Energy Transfer from Quantum Dots to Molecules
Part of Journal of the American Chemical Society, p. 17581-17588, 2020
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Part of The Journal of Chemical Physics, 2020
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Part of The Journal of Physical Chemistry C, p. 20794-20805, 2020
- DOI for Singlet Fission and Electron Injection from the Triplet Excited State in Diphenylisobenzofuran–Semiconductor Assemblies: Effects of Solvent Polarity and Driving Force
- Download full text (pdf) of Singlet Fission and Electron Injection from the Triplet Excited State in Diphenylisobenzofuran–Semiconductor Assemblies: Effects of Solvent Polarity and Driving Force
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Optimizing photon upconversion by decoupling excimer formation and triplet triplet annihilation
Part of Physical Chemistry, Chemical Physics - PCCP, p. 1715-1720, 2020
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Part of Journal of the American Chemical Society, p. 12907-12915, 2019
- DOI for Engineering Molecular Ligand Shells on Quantum Dots for Quantitative Harvesting of Triplet Excitons Generated by Singlet Fission
- Download full text (pdf) of Engineering Molecular Ligand Shells on Quantum Dots for Quantitative Harvesting of Triplet Excitons Generated by Singlet Fission
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Part of Journal of Physical Chemistry B, p. 9934-9943, 2019
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Part of Chemical Science, p. 4750-4760, 2019
- DOI for Photon upconversion utilizing energy beyond the band gap of crystalline silicon with a hybrid TES-ADT/PbS quantum dots system
- Download full text (pdf) of Photon upconversion utilizing energy beyond the band gap of crystalline silicon with a hybrid TES-ADT/PbS quantum dots system
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Part of ACS Materials Letters, p. 660-664, 2019
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Part of The Journal of Physical Chemistry Letters, p. 4713-4719, 2019
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Part of Journal of the American Chemical Society, p. 9578-9584, 2019