Shylin group

Photocatalytic and electrocatalytic energy and chemical conversion
Our research
Our research focuses on developing photo- and electrochemical approaches to small molecules activation. We combine synthetic inorganic chemistry with state-of-the-art characterization techniques. Specifically, we use electrochemistry methods, conventional and advanced spectroscopy, crystallography, mass spectrometry and other methods to study mechanisms of catalysis and characterization of intermediates. The special attention is given to the role of high-valent transition metal species in the activation of small molecules.
Research project
Group members
Publications
Part of Acta Crystallographica Section E, p. 25-28, 2024
- DOI for Crystal structure of a water oxidation catalyst solvate with composition (NH4)2[FeIV(L-6H)]·3CH3COOH (L = clathrochelate ligand)
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Nature of cyanoargentate bridges defining spin crossover in new 2D Hofmann clathrate analogues
Part of Dalton Transactions, p. 4251-4259, 2024
Part of Dalton Transactions, p. 9062-9071, 2024
Enzymatic N2 activation: general discussion
Part of Faraday discussions, p. 287-295, 2023
Electrocatalytic and photocatalytic routes to N2 activation: general discussion
Part of Faraday discussions, p. 402-428, 2023
Alternative routes to NH3 and its application: general discussion
Part of Faraday discussions, p. 549-556, 2023
Cooperative Spin Crossover above Room Temperature in the Iron(II) Cyanoborohydride–Pyrazine Complex
Part of Inorganic Chemistry, p. 14761-14769, 2022
Water Oxidation by Pentapyridyl Base Metal Complexes?: A Case Study
Part of Inorganic Chemistry, p. 9104-9118, 2022
- DOI for Water Oxidation by Pentapyridyl Base Metal Complexes?: A Case Study
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High-Temperature Superconductivity in Hydrides: Experimental Evidence and Details
Part of Journal of Superconductivity and Novel Magnetism, p. 965-977, 2022
- DOI for High-Temperature Superconductivity in Hydrides: Experimental Evidence and Details
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Part of Inorganic Chemistry, p. 2093-2104, 2022
Four‐Step Spin Crossover in a New Cyano‐Bridged Iron‐Silver Coordination Polymer
Part of Chemistry - A European Journal, 2022
1D iron(II)-1,2,4-triazolic chains with spin crossover assembled from discrete trinuclear complexes
Part of Dalton Transactions, p. 2364-2369, 2022
- DOI for 1D iron(II)-1,2,4-triazolic chains with spin crossover assembled from discrete trinuclear complexes
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Part of Dalton Transactions, p. 660-674, 2021
- DOI for Electronic and geometric structure effects on one-electron oxidation of first-row transition metals in the same ligand framework
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Part of RSC Advances, p. 32119-32125, 2021
- DOI for Hybrid compound based on diethylenetriaminecopper(ii) cations and scarce V-monosubstituted β-octamolybdate as water oxidation catalyst
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Spin crossover in iron(ii) Hofmann clathrates analogues with 1,2,3-triazole
Part of Dalton Transactions, p. 9250-9258, 2021
Understanding the Stability and Recrystallization Behavior of Amorphous Zinc Phosphate
Part of The Journal of Physical Chemistry C, p. 2636-2647, 2021
Part of Chemical Communications, p. 11060-11063, 2021
Spin transition in a ferrous chloride complex supported by a pentapyridine ligand
Part of Chemical Communications, p. 2703-2706, 2020
- DOI for Spin transition in a ferrous chloride complex supported by a pentapyridine ligand
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Facile one-pot synthesis of hybrid compounds based on decavanadate showing water oxidation activity
Part of Inorganic Chemistry Communications, 2020
Part of Inorganic Chemistry, p. 6541-6549, 2020
- DOI for Hofmann-Like Frameworks Fe(2-methylpyrazine)n[M(CN)2]2 (M = Au, Ag): Spin-Crossover Defined by the Precious Metal
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Beyond artificial photosynthesis: general discussion
Part of Faraday discussions, p. 422-438, 2019
Synthetic approaches to artificial photosynthesis: general discussion
Part of Faraday discussions, p. 242-281, 2019
Biological approaches to artificial photosynthesis: general discussion
Part of Faraday discussions, p. 66-83, 2019
Part of Inorganic Chemistry Frontiers, p. 1813-1823, 2019
- DOI for Copper-containing hybrid compounds based on extremely rare [V2Mo6O26]6- POM as water oxidation catalysts
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Part of Faraday discussions, p. 162-174, 2019
- DOI for Photoinduced hole transfer from tris(bipyridine)ruthenium dye to a high-valent iron-based water oxidation catalyst
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Efficient visible light-driven water oxidation catalysed by an iron(IV) clathrochelate complex
Part of Chemical Communications, p. 3335-3338, 2019
- DOI for Efficient visible light-driven water oxidation catalysed by an iron(IV) clathrochelate complex
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Part of ChemCatChem, p. 2949-2954, 2018
Indefinitely stable iron(IV) cage complexes formed in water by air oxidation
Part of Nature Communications, 2017
- DOI for Indefinitely stable iron(IV) cage complexes formed in water by air oxidation
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Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system
Part of Nature, p. 73-76, 2015
Contact
- If you have any questions regarding our research, you are welcome to contact research leader Sergii Shylin.
- Sergii Shylin