Leif Hammarströms grupp

Ultrafast Electron Transfer from CuInS₂ Quantum Dots to a Molecular Catalyst for Hydrogen Production: Challenging Diffusion Limitations

Bagnall, Andrew J.; Eliasson, Nora; Hansson, Sofie; Chavarot-Kerlidou, Murielle et al.

Ingår i ACS Catalysis, s. 4186-4201, 2024

• DOI för Ultrafast Electron Transfer from CuInS₂ Quantum Dots to a Molecular Catalyst for Hydrogen Production: Challenging Diffusion Limitations
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Multi-Variable Multi-Metric Optimization of Self-Assembled Photocatalytic CO₂ Reduction Performance Using Machine Learning Algorithms

Bonke, Shannon A.; Trezza, Giovanni; Bergamasco, Luca; Song, Hongwei et al.

Ingår i Journal of the American Chemical Society, s. 15648-15658, 2024

• DOI för Multi-Variable Multi-Metric Optimization of Self-Assembled Photocatalytic CO₂ Reduction Performance Using Machine Learning Algorithms
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Directed ultrafast conformational changes accompany electron transfer in a photolyase as resolved by serial crystallography

Cellini, Andrea; Shankar, Madan Kumar; Nimmrich, Amke; Hunt, Leigh Anna et al.

Ingår i Nature Chemistry, s. 624-632, 2024

• DOI för Directed ultrafast conformational changes accompany electron transfer in a photolyase as resolved by serial crystallography
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Direct Detection of Key Intermediates during the Product Release in Rhenium Bipyridine-Catalyzed CO₂ Reduction Reaction

Chattopadhyay, Samir; Cheah, Mun Hon; Lomoth, Reiner; Hammarström, Leif

Ingår i ACS Catalysis, s. 16324-16334, 2024

• DOI för Direct Detection of Key Intermediates during the Product Release in Rhenium Bipyridine-Catalyzed CO₂ Reduction Reaction
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Embedding biocatalysts in a redox polymer enhances the performance of dye-sensitized photocathodes in bias-free photoelectrochemical water splitting

Cheng, Fangwen; Pavliuk, Olha; Hardt, Steffen; Hunt, Leigh Anna et al.

Ingår i Nature Communications, 2024

• DOI för Embedding biocatalysts in a redox polymer enhances the performance of dye-sensitized photocathodes in bias-free photoelectrochemical water splitting
• Ladda ner fulltext (pdf) av Embedding biocatalysts in a redox polymer enhances the performance of dye-sensitized photocathodes in bias-free photoelectrochemical water splitting

Enter Mn^IV-NHC: A Dark Photooxidant with a Long-Lived Charge-Transfer Excited State

Kaul, Nidhi; Asempa, Eyram; Valdez-Moreira, Juan A.; Smith, Jeremy M. et al.

Ingår i Journal of the American Chemical Society, s. 24619-24629, 2024

• DOI för Enter Mn^IV-NHC: A Dark Photooxidant with a Long-Lived Charge-Transfer Excited State
• Ladda ner fulltext (pdf) av Enter Mn^IV-NHC: A Dark Photooxidant with a Long-Lived Charge-Transfer Excited State

Realizing Symmetry-Breaking Architectures in Soap Films

Kaul, Nidhi; Bergamasco, Luca; Song, Hongwei; Varkevisser, Thijs et al.

Ingår i Physical Review Letters, 2024

• DOI för Realizing Symmetry-Breaking Architectures in Soap Films
• Ladda ner fulltext (pdf) av Realizing Symmetry-Breaking Architectures in Soap Films

Switching the proton-coupled electron transfer mechanism for non-canonical tyrosine residues in a de novo protein

Nilsen-Moe, Astrid; Reinhardt, Clorice R.; Huang, Ping; Agarwala, Hemlata et al.

Ingår i Chemical Science, s. 3957-3970, 2024

• DOI för Switching the proton-coupled electron transfer mechanism for non-canonical tyrosine residues in a de novo protein
• Ladda ner fulltext (pdf) av Switching the proton-coupled electron transfer mechanism for non-canonical tyrosine residues in a de novo protein

Meta-Ortho Effect on the Excited State Pathways of Chloroanilines

Nitu, Cristina; van der Wal, Jacob Jan; Kaul, Nidhi; Steen, Jorn D. et al.

Ingår i European Journal of Organic Chemistry, 2024

• DOI för Meta-Ortho Effect on the Excited State Pathways of Chloroanilines
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β-Scission of Secondary Alcohols via Photosensitization: Synthetic Utilization and Mechanistic Insights

Patehebieke, Yeersen; Charaf, Rima; Bryce-Rogers, Hogan P.; Ye, Ke et al.

Ingår i ACS Catalysis, s. 585-593, 2024

• DOI för β-Scission of Secondary Alcohols via Photosensitization: Synthetic Utilization and Mechanistic Insights
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Access to long-lived room temperature phosphorescence through auration of 2,1,3-benzothiadiazole

Posada Urrutia, Mauricio; Kaul, Nidhi; Kaper, Tobias; Hurrell, Dustin et al.

Ingår i Dalton Transactions, s. 5658-5664, 2024

• DOI för Access to long-lived room temperature phosphorescence through auration of 2,1,3-benzothiadiazole
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Mechanistic Insights and Synthetic Explorations of the Photoredox-Catalyzed Activation of Halophosphines

Arkhypchuk, Anna I.; Tran, Thuan T.; Charaf, Rima; Hammarström, Leif et al.

Ingår i Inorganic Chemistry, s. 18391-18398, 2023

• DOI för Mechanistic Insights and Synthetic Explorations of the Photoredox-Catalyzed Activation of Halophosphines
• Ladda ner fulltext (pdf) av Mechanistic Insights and Synthetic Explorations of the Photoredox-Catalyzed Activation of Halophosphines

Mechanistic Insights into the Photocatalytic Hydrogen Production of Y5 and Y6 Nanoparticles

Brnovic, Andjela; Hammarström, Leif; Tian, Haining

Ingår i The Journal of Physical Chemistry C, s. 12631-12639, 2023

• DOI för Mechanistic Insights into the Photocatalytic Hydrogen Production of Y5 and Y6 Nanoparticles
• Ladda ner fulltext (pdf) av Mechanistic Insights into the Photocatalytic Hydrogen Production of Y5 and Y6 Nanoparticles

Elucidating Electron Transfer Kinetics and Optimizing System Performance for Escherichia coli-Based Semi-Artificial H-2 Production

Gamache, Mira T.; Charaf, Rima; Kurth, Larissa; Filmon, Dawit T. et al.

Ingår i ACS Catalysis, s. 9476-9486, 2023

• DOI för Elucidating Electron Transfer Kinetics and Optimizing System Performance for Escherichia coli-Based Semi-Artificial H-2 Production
• Ladda ner fulltext (pdf) av Elucidating Electron Transfer Kinetics and Optimizing System Performance for Escherichia coli-Based Semi-Artificial H-2 Production

Excited-state and charge-carrier dynamics in binary conjugated polymer dots towards efficient photocatalytic hydrogen evolution

Liu, Aijie; Wang, Sicong; Song, Hongwei; Liu, Yawen et al.

Ingår i Physical Chemistry, Chemical Physics - PCCP, s. 2935-2945, 2023

• DOI för Excited-state and charge-carrier dynamics in binary conjugated polymer dots towards efficient photocatalytic hydrogen evolution
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Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects

Suremann, Nina F.; McCarthy, Brian D.; Gschwind, Wanja; Kumar, Amol et al.

Ingår i Chemical Reviews, s. 6545-6611, 2023

• DOI för Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects
• Ladda ner fulltext (pdf) av Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects

Charge Recombination Deceleration by Lateral Transfer of Electrons in Dye-Sensitized NiO Photocathode

Ye, Chen; Cheng, Haoliang; Wrede, Sina; Diring, Steiphane et al.

Ingår i Journal of the American Chemical Society, s. 11067-11073, 2023

• DOI för Charge Recombination Deceleration by Lateral Transfer of Electrons in Dye-Sensitized NiO Photocathode
• Ladda ner fulltext (pdf) av Charge Recombination Deceleration by Lateral Transfer of Electrons in Dye-Sensitized NiO Photocathode

A Bidirectional Bioinspired [FeFe]-Hydrogenase Model

Ahmed, Md Estak; Nayek, Abhijit; Krizan, Alenka; Coutard, Nathan et al.

Ingår i Journal of the American Chemical Society, s. 3614-3625, 2022

• DOI för A Bidirectional Bioinspired [FeFe]-Hydrogenase Model

Assessing the effect of surface states of mesoporous NiO films on charge transport and unveiling an unexpected light response phenomenon in tandem dye-sensitized solar cells

Cheng, Haoliang; Ayaz, Muhammad; Wrede, Sina; Boschloo, Gerrit et al.

Ingår i Energy Advances, s. 303-311, 2022

• DOI för Assessing the effect of surface states of mesoporous NiO films on charge transport and unveiling an unexpected light response phenomenon in tandem dye-sensitized solar cells
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Gold nanoparticle-based supramolecular approach for dye-sensitized H-2-evolving photocathodes

Lalaoui, Noemie; Abdellah, Mohamed; Materna, Kelly L.; Xu, Bo et al.

Ingår i Dalton Transactions, s. 15716-15724, 2022

• DOI för Gold nanoparticle-based supramolecular approach for dye-sensitized H-2-evolving photocathodes
• Ladda ner fulltext (pdf) av Gold nanoparticle-based supramolecular approach for dye-sensitized H-2-evolving photocathodes

Sustainable Ir-Photoredox Catalysis by Means of Heterogenization

Lindroth, Rickard; Materna, Kelly L.; Hammarström, Leif; Wallentin, Carl-Johan

Ingår i ACS ORGANIC & INORGANIC AU, s. 427-432, 2022

• DOI för Sustainable Ir-Photoredox Catalysis by Means of Heterogenization
• Ladda ner fulltext (pdf) av Sustainable Ir-Photoredox Catalysis by Means of Heterogenization

Concerted and Stepwise Proton-Coupled Electron Transfer for Tryptophan-Derivative Oxidation with Water as the Primary Proton Acceptor: Clarifying a Controversy

Nilsen-Moe, Astrid; Rosichini, Andrea; Glover, Starla; Hammarström, Leif

Ingår i Journal of the American Chemical Society, s. 7308-7319, 2022

• DOI för Concerted and Stepwise Proton-Coupled Electron Transfer for Tryptophan-Derivative Oxidation with Water as the Primary Proton Acceptor: Clarifying a Controversy
• Ladda ner fulltext (pdf) av Concerted and Stepwise Proton-Coupled Electron Transfer for Tryptophan-Derivative Oxidation with Water as the Primary Proton Acceptor: Clarifying a Controversy

Proton-coupled energy transfer in molecular triads

Pettersson-Rimgard, Belinda; Tao, Zhen; Parada, Giovanny A.; Cotter, Laura F. et al.

Ingår i Science, s. 742-746, 2022

• DOI för Proton-coupled energy transfer in molecular triads

Self-Assembled Liposomes Enhance Electron Transfer for Efficient Photocatalytic CO2 Reduction

Rodriguez-Jimenez, Santiago; Song, Hongwei; Lam, Erwin; Wright, Demelza et al.

Ingår i Journal of the American Chemical Society, s. 9399-9412, 2022

• DOI för Self-Assembled Liposomes Enhance Electron Transfer for Efficient Photocatalytic CO2 Reduction
• Ladda ner fulltext (pdf) av Self-Assembled Liposomes Enhance Electron Transfer for Efficient Photocatalytic CO2 Reduction

The 2022 solar fuels roadmap

Segev, Gideon; Kibsgaard, Jakob; Hahn, Christopher; Xu, Zhichuan J. et al.

Ingår i Journal of Physics D, 2022

• DOI för The 2022 solar fuels roadmap
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Strategies for Switching the Mechanism of Proton-Coupled Electron Transfer Reactions Illustrated by Mechanistic Zone Diagrams

Tyburski, Robin; Hammarström, Leif

Ingår i Chemical Science, 2022

• DOI för Strategies for Switching the Mechanism of Proton-Coupled Electron Transfer Reactions Illustrated by Mechanistic Zone Diagrams
• Ladda ner fulltext (pdf) av Strategies for Switching the Mechanism of Proton-Coupled Electron Transfer Reactions Illustrated by Mechanistic Zone Diagrams

Electron-hopping across dye-sensitized mesoporous NiO surfaces

Wrede, Sina; He, Lanlan; Boschloo, Gerrit; Hammarström, Leif et al.

Ingår i Physical Chemistry, Chemical Physics - PCCP, s. 29850-29861, 2022

• DOI för Electron-hopping across dye-sensitized mesoporous NiO surfaces
• Ladda ner fulltext (pdf) av Electron-hopping across dye-sensitized mesoporous NiO surfaces

Nanotechnology for catalysis and solar energy conversion

Banin, U.; Waiskopf, N.; Hammarström, Leif; Boschloo, Gerrit et al.

Ingår i Nanotechnology, 2021

• DOI för Nanotechnology for catalysis and solar energy conversion
• Ladda ner fulltext (pdf) av Nanotechnology for catalysis and solar energy conversion

Solvent and Temperature Effects on Photoinduced Proton-Coupled Electron Transfer in the Marcus Inverted Region

Cotter, Laura F.; Pettersson-Rimgard, Belinda; Parada, Giovanny A.; Mayer, James M. et al.

Ingår i Journal of Physical Chemistry A, s. 7670-7684, 2021

• DOI för Solvent and Temperature Effects on Photoinduced Proton-Coupled Electron Transfer in the Marcus Inverted Region
• Ladda ner fulltext (pdf) av Solvent and Temperature Effects on Photoinduced Proton-Coupled Electron Transfer in the Marcus Inverted Region

From NiMoO₄ to γ-NiOOH: Detecting the Active Catalyst Phase by Time Resolved in Situ and Operando Raman Spectroscopy

Dürr, Robin N.; Maltoni, Pierfrancesco; Tian, Haining; Jousselme, Bruno et al.

Ingår i ACS Nano, s. 13504-13515, 2021

• DOI för From NiMoO₄ to γ-NiOOH: Detecting the Active Catalyst Phase by Time Resolved in Situ and Operando Raman Spectroscopy
• Ladda ner fulltext (pdf) av From NiMoO₄ to γ-NiOOH: Detecting the Active Catalyst Phase by Time Resolved in Situ and Operando Raman Spectroscopy

Ultrafast Dynamics in Cu-Deficient CuInS2 Quantum Dots: Sub-Bandgap Transitions and Self-Assembled Molecular Catalysts

Eliasson, Nora; Pettersson-Rimgard, Belinda; Castner, Ashleigh T.; Tai, Cheuk-Wai et al.

Ingår i The Journal of Physical Chemistry C, s. 14751-14764, 2021

• DOI för Ultrafast Dynamics in Cu-Deficient CuInS2 Quantum Dots: Sub-Bandgap Transitions and Self-Assembled Molecular Catalysts
• Ladda ner fulltext (pdf) av Ultrafast Dynamics in Cu-Deficient CuInS2 Quantum Dots: Sub-Bandgap Transitions and Self-Assembled Molecular Catalysts

Panchromatic Ternary Polymer Dots Involving Sub-Picosecond Energy and Charge Transfer for Efficient and Stable Photocatalytic Hydrogen Evolution

Liu, Aijie; Gedda, Lars; Axelsson, Martin; Pavliuk, Mariia et al.

Ingår i Journal of the American Chemical Society, s. 2875-2885, 2021

• DOI för Panchromatic Ternary Polymer Dots Involving Sub-Picosecond Energy and Charge Transfer for Efficient and Stable Photocatalytic Hydrogen Evolution
• Ladda ner fulltext (pdf) av Panchromatic Ternary Polymer Dots Involving Sub-Picosecond Energy and Charge Transfer for Efficient and Stable Photocatalytic Hydrogen Evolution

Photoredox Catalysis Using Heterogenized Iridium Complexes**

Materna, Kelly L.; Hammarström, Leif

Ingår i Chemistry - A European Journal, s. 16966-16977, 2021

• DOI för Photoredox Catalysis Using Heterogenized Iridium Complexes**

Roadmap towards solar fuel synthesis at the water interface of liposome membranes dagger

Pannwitz, Andrea; Klein, David M.; Rodriguez-Jimenez, Santiago; Casadevall, Carla et al.

Ingår i Chemical Society Reviews, s. 4833-4855, 2021

• DOI för Roadmap towards solar fuel synthesis at the water interface of liposome membranes dagger
• Ladda ner fulltext (pdf) av Roadmap towards solar fuel synthesis at the water interface of liposome membranes dagger

Molecular Triad Containing a TEMPO Catalyst Grafted on Mesoporous Indium Tin Oxide as a Photoelectrocatalytic Anode for Visible Light-Driven Alcohol Oxidation

Pati, Palas Baran; Abdellah, Mohamed; Diring, Stephane; Hammarström, Leif et al.

Ingår i ChemSusChem, s. 2902-2913, 2021

• DOI för Molecular Triad Containing a TEMPO Catalyst Grafted on Mesoporous Indium Tin Oxide as a Photoelectrocatalytic Anode for Visible Light-Driven Alcohol Oxidation

Electrochemical, Spectroscopic, and Computational Investigation of a Series of Polypyridyl Ruthenium(II) Complexes: Characterization of Reduced States

Queyriaux, Nicolas; Esmieu, Charlène; Gupta, Arvind Kumar; Vendier, Laure et al.

Ingår i European Journal of Inorganic Chemistry, s. 1263-1270, 2021

• DOI för Electrochemical, Spectroscopic, and Computational Investigation of a Series of Polypyridyl Ruthenium(II) Complexes: Characterization of Reduced States

Imidazolium-modification enhances photocatalytic CO2 reduction on ZnSe quantum dots

Sahm, Constantin D.; Mates-Torres, Eric; Eliasson, Nora; Sokolowski, Kamil et al.

Ingår i Chemical Science, s. 9078-9087, 2021

• DOI för Imidazolium-modification enhances photocatalytic CO2 reduction on ZnSe quantum dots
• Ladda ner fulltext (pdf) av Imidazolium-modification enhances photocatalytic CO2 reduction on ZnSe quantum dots

Proton-Coupled Electron Transfer Guidelines, Fair and Square

Tyburski, Robin; Liu, Tianfei; Glover, Starla; Hammarström, Leif

Ingår i Journal of the American Chemical Society, s. 560-576, 2021

• DOI för Proton-Coupled Electron Transfer Guidelines, Fair and Square
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Photoinduced Fano Resonances between Quantum Confined Nanocrystals and Adsorbed Molecular Catalysts

Yang, Wenxing; Liu, Yawei; Edvinsson, Tomas; Castner, Ashleigh T. et al.

Ingår i Nano Letters, s. 5813-5818, 2021

• DOI för Photoinduced Fano Resonances between Quantum Confined Nanocrystals and Adsorbed Molecular Catalysts

Self-Recovery of Photochemical H₂ Evolution with a Molecular Diiron Catalyst Incorporated in a UiO-66 Metal-Organic Framework

Bozal-Ginesta, Carlota; Pullen, Sonja; Ott, Sascha; Hammarström, Leif

Ingår i ChemPhotoChem, s. 287-290, 2020

• DOI för Self-Recovery of Photochemical H₂ Evolution with a Molecular Diiron Catalyst Incorporated in a UiO-66 Metal-Organic Framework

A Comparative Investigation of the Role of the Anchoring Group on Perylene Monoimide Dyes in NiO-Based Dye-Sensitized Solar Cells

Farré, Yoann; Maschietto, Federica; Föhlinger, Jens; Wykes, Mike et al.

Ingår i ChemSusChem, s. 1844-1855, 2020

• DOI för A Comparative Investigation of the Role of the Anchoring Group on Perylene Monoimide Dyes in NiO-Based Dye-Sensitized Solar Cells

Understanding the Performance of NiO Photocathodes with Alkyl-Derivatized Cobalt Catalysts and a Push-Pull Dye

Materna, Kelly L.; Beiler, Anna M.; Thapper, Anders; Ott, Sascha et al.

Ingår i ACS Applied Materials and Interfaces, s. 31372-31381, 2020

• DOI för Understanding the Performance of NiO Photocathodes with Alkyl-Derivatized Cobalt Catalysts and a Push-Pull Dye
• Ladda ner fulltext (pdf) av Understanding the Performance of NiO Photocathodes with Alkyl-Derivatized Cobalt Catalysts and a Push-Pull Dye

Using Surface Amide Couplings to Assemble Photocathodes for Solar Fuel Production Applications

Materna, Kelly L.; Lalaoui, Noémie; Laureanti, Joseph A.; Walsh, Aaron P. et al.

Ingår i ACS Applied Materials and Interfaces, s. 4501-4509, 2020

• DOI för Using Surface Amide Couplings to Assemble Photocathodes for Solar Fuel Production Applications

Proton-Coupled Electron Transfer from Tyrosine in the Interior of a de novo Protein: Mechanisms and Primary Proton Acceptor

Nilsen-Moe, Astrid; Reinhardt, Clorice R.; Glover, Starla D.; Liang, Li et al.

Ingår i Journal of the American Chemical Society, s. 11550-11559, 2020

• DOI för Proton-Coupled Electron Transfer from Tyrosine in the Interior of a de novo Protein: Mechanisms and Primary Proton Acceptor
• Ladda ner fulltext (pdf) av Proton-Coupled Electron Transfer from Tyrosine in the Interior of a de novo Protein: Mechanisms and Primary Proton Acceptor

From non-innocent to guilty: on the role of redox-active ligands in the electro-assisted reduction of CO₂ mediated by a cobalt(ii)-polypyridyl complex

Queyriaux, Nicolas; Abel, K.; Fize, J.; Pecaut, J. et al.

Ingår i Sustainable Energy & Fuels, s. 3668-3676, 2020

• DOI för From non-innocent to guilty: on the role of redox-active ligands in the electro-assisted reduction of CO₂ mediated by a cobalt(ii)-polypyridyl complex
• Ladda ner fulltext (pdf) av From non-innocent to guilty: on the role of redox-active ligands in the electro-assisted reduction of CO₂ mediated by a cobalt(ii)-polypyridyl complex

Excited-state proton-coupled electron transfer within ion pairs

Swords, Wesley B.; Meyer, Gerald J.; Hammarström, Leif

Ingår i Chemical Science, s. 3460-3473, 2020

• DOI för Excited-state proton-coupled electron transfer within ion pairs
• Ladda ner fulltext (pdf) av Excited-state proton-coupled electron transfer within ion pairs

Understanding the Role of Surface States on Mesoporous NiO Films

Tian, Lei; Tyburski, Robin; Wen, Chenyu; Sun, Rui et al.

Ingår i Journal of the American Chemical Society, 2020

• DOI för Understanding the Role of Surface States on Mesoporous NiO Films

The reactivity of molecular oxygen and reactive oxygen species with [FeFe] hydrogenase biomimetics: reversibility and the role of the second coordination sphere

Wang, Vincent Cho-Chien; Esmieu, Charlène; Redman, Holly J.; Berggren, Gustav et al.

Ingår i Dalton Transactions, s. 858-865, 2020

• DOI för The reactivity of molecular oxygen and reactive oxygen species with [FeFe] hydrogenase biomimetics: reversibility and the role of the second coordination sphere
• Ladda ner fulltext (pdf) av The reactivity of molecular oxygen and reactive oxygen species with [FeFe] hydrogenase biomimetics: reversibility and the role of the second coordination sphere

Metal vs. ligand protonation and the alleged proton-shuttling role of the azadithiolate ligand in catalytic H-2 formation with FeFe hydrogenase model complexes

Aster, Alexander; Wang, Shihuai; Mirmohades, Mohammad; Esmieu, Charlène et al.

Ingår i Chemical Science, s. 5582-5588, 2019

• DOI för Metal vs. ligand protonation and the alleged proton-shuttling role of the azadithiolate ligand in catalytic H-2 formation with FeFe hydrogenase model complexes
• Ladda ner fulltext (pdf) av Metal vs. ligand protonation and the alleged proton-shuttling role of the azadithiolate ligand in catalytic H-2 formation with FeFe hydrogenase model complexes

A heavy metal-free CuInS2 quantum dot sensitized NiO photocathode with a Re molecular catalyst for photoelectrochemical CO2 reduction

Huang, Jing; Xu, Bo; Tian, Lei; Pati, Palas Baran et al.

Ingår i Chemical Communications, s. 7918-7921, 2019

• DOI för A heavy metal-free CuInS2 quantum dot sensitized NiO photocathode with a Re molecular catalyst for photoelectrochemical CO2 reduction
• Ladda ner fulltext (pdf) av A heavy metal-free CuInS2 quantum dot sensitized NiO photocathode with a Re molecular catalyst for photoelectrochemical CO2 reduction